
Chakraborty Research Laboratory
Organometallics, Homogeneous Catalysis, Sustainability
Publications
(34) Anand, A.; Regina, A.; Jalwal, S.; Prodhan, S.; Sil, D.; Paranjothy, M.; Chakraborty, S., Chromium Catalyzed Acceptorless Dehydrogenative (Cross)Coupling of Primary Amines to Secondary Imines. Dalton Trans. 2025, DOI:10.1039/D4DT03460K.
(33) Singh, T.; Chakraborty, S.; Chromium Catalyzed Transfer Hydrogenation of CO2 to Formate Using Isopropanol Under Ambient Pressure, Catal. Sci. Technol., 2025, 15, 689-695.
(32) Jalwal S.; Das S.; and Chakraborty, S.; Terpenylation of Ketones and Secondary Alcohol Under Hydrogen Borrowing Manganese Catalysis, J. Org. Chem., 2025. 90, 309-316.
(31) Atreya, V.; Jalwal S.; and Chakraborty, S.; Chromium Catalyzed Sustainable C-C and C-N Bond Formation: C-Alkylation and Friedländer Quinoline Synthesis Using Alcohols, Dalton Trans, 2025, 54, 1212-1221.
(30) Singh T.; Gutal A.; Regina A.; Banerjee A.; Paranjothy M.; Chakraborty S.; Bench-Stable Low-Valent Chromium Catalysts for Hydrogenation of CO2, Bicarbonate, and Inorganic Carbonates to Formate. ACS Catal. 2024, 14, 14958–14965.
(29) Singh, T.; Chakraborty, S.; Molybdenum Catalyzed Hydrogenation of Carbon dioxide, Bicarbonate, and Inorganic Carbonates to Formate. Dalton Trans. 2024, 53, 10244-10249.
(28) Jalwal S.; Regina A.; Atreya V.; Paranjothya M.; Chakraborty S.; NNN Manganese Complex Catalyzed α-Alkylation of Methyl ketones using Alcohols: An Experimental and Computational study. Dalton Trans. 2024, 53, 3236-3243.
(27) Singh T.; Atreya V.; Jalwal S.; Anand A.; Chakraborty S.; Advances in Group VI Metals Catalysed Homogeneous Hydrogenation and Dehydrogenation Reactions. Chem. Asian J. 2023, 18, e202300758.
(26) Singh, K.; Raj, R.; Rajagopal, A.K.; Jalwal, S.; Chakraborty, S.; Shock wave attenuation using sandwiched structures made up of polymer foams and shear thickening fluid. J. Mech. Sci. Technol . 2023, 37, 1311-1316.
(25) Singh, T.; Jalwal, S.; Chakraborty, S. Homogeneous First‐row Transition‐metal‐catalyzed Carbon Dioxide Hydrogenation to Formic Acid/Formate, and Methanol. Asian J. Org. Chem. 2022, e202200330 (Invited Review).
(24) Jalwal, S.; Atreya, V.; Singh, T.; Chakraborty, S. Base Metal Catalyzed (De)Hydrogenative Formylation and Methylation Reactions Utilizing Carbon Dioxide and Methanol as C1 Sources. Tetrahedron Lett. 2021, 82, 153362 (Invited Review).
Post. Doc. & Ph.D.
(23) Kumar, A.; Janes, T.; Chakraborty, S.; Daw, P.; von Wolff, N.; Carmieli, R.; Diskin-Posner, Y.; Milstein, D. C−C Bond Formation of Benzyl Alcohols and Alkynes Using a Catalytic Amount of KO t Bu: Unusual Regioselectivity through a Radical Mechanism. Angew. Chem. Int. Ed. 2019, 58 , 3373–3377.
(22) Chakraborty, S.; Daw, P.; Ben David, Y.; Milstein, D. Manganese-Catalyzed α-Alkylation of Ketones, Esters, and Amides Using Alcohols. ACS Catal. 2018, 8 , 10300–10305.
(21) Das, U. K.; Chakraborty, S.; Diskin-Posner, Y.; Milstein, D. Direct Conversion of Alcohols into Alkenes by Dehydrogenative Coupling with Hydrazine/Hydrazone Catalyzed by Manganese. Angew. Chem. Int. Ed. 2018, 130, 13632–13636.
(20) Zou, Y.-Q.; Chakraborty, S.; Nerush, A.; Oren, D.; Diskin-Posner, Y.; Ben-David, Y.; Milstein, D. Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation. ACS Catal. 2018, 8 (9), 8014–8019.
(19) Chakraborty, S.; Das, U. K.; Ben-David, Y.; Milstein, D. Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols. J. Am. Chem. Soc. 2017, 139 (34), 11710–11713.
(18) Bauer, J. O.; Chakraborty, S.; Milstein, D. Manganese-Catalyzed Direct Deoxygenation of Primary Alcohols. ACS Catal. 2017, 7 (7), 4462–4466.
(17) Chakraborty, S.; Milstein, D. Selective Hydrogenation of Nitriles to Secondary Imines Catalyzed by an Iron Pincer Complex. ACS Catal. 2017, 7 (6), 3968–3972.
(16) Chakraborty, S.; Gellrich, U.; Diskin-Posner, Y.; Leitus, G.; Avram, L.; Milstein, D. Manganese-Catalyzed N-Formylation of Amines by Methanol Liberating H 2 : A Catalytic and Mechanistic Study. Angew. Chem. Int. Ed. 2017, 129 (15), 4293–4297.
(15) Chakraborty, S.; Leitus, G.; Milstein, D. Iron-Catalyzed Mild and Selective Hydrogenative Cross-Coupling of Nitriles and Amines To Form Secondary Aldimines. Angew. Chem. Int. Ed. 2017, 129 (8), 2106–2110.
(14) Daw, P.; Chakraborty, S.; Leitus, G.; Diskin-Posner, Y.; Ben-David, Y.; Milstein, D. Selective N -Formylation of Amines with H 2 and CO 2 Catalyzed by Cobalt Pincer Complexes. ACS Catal. 2017, 7, 2500–2504.
(13) Daw, P.; Chakraborty, S.; Garg, J. A.; Ben-David, Y.; Milstein, D. Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes. Angew. Chem. Int. Ed. 2016, 55, 14373–14377.
(12) Rivada-Wheelaghan, O.; Chakraborty, S.; Shimon, L. J. W.; Ben-David, Y.; Milstein, D. Z -Selective (Cross-)Dimerization of Terminal Alkynes Catalyzed by an Iron Complex. Angew. Chem. Int. Ed. 2016, 55 , 6942–6945.
(11) Chakraborty, S.; Leitus, G.; Milstein, D. Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Novel Iron Complex. Chem. Commun. 2016, 52, 1812–1815.
(10) Garg, J. A.; Chakraborty, S.; Ben-David, Y.; Milstein, D. Unprecedented Iron-Catalyzed Selective Hydrogenation of Activated Amides to Amines and Alcohols. Chem. Commun. 2016, 52, 5285–5288.
(9) Chakraborty, S.; Kunjanpillai, R.; Blacque, O.; Berke, H. Ullmann‐Type and Related Redox Reactions of Nitrosyl Molybdenum Complexes Bearing a Large‐Bite‐Angle Diphosphine. Eur. J. Inorg. Chem. 2016, 2016 (1), 103–110.
(8) Mukherjee, A.; Srimani, D.; Chakraborty, S.; Ben-David, Y.; Milstein, D. Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Cobalt Pincer Complex. J. Am. Chem. Soc. 2015, 137 , 8888–8891.
(7) Chakraborty, S.; Blacque, O.; Berke, H. Ligand Assisted Carbon Dioxide Activation and Hydrogenation Using Molybdenum and Tungsten Amides. Dalton Trans. 2015, 44, 6560–6570.
(6) Chakraborty, S.; Blacque, O.; Fox, T.; Berke, H. Trisphosphine-Chelate-Substituted Molybdenum and Tungsten Nitrosyl Hydrides as Highly Active Catalysts for Olefin Hydrogenations. Chem. - Eur. J. 2014, 20, 12641–12654.
(5) Chakraborty, S.; Blacque, O.; Fox, T.; Berke, H. Hydrogenation of Imines Catalyzed by Trisphosphine-Substituted Molybdenum and Tungsten Nitrosyl Hydrides and Co-Catalytic Acid. Chem. - Asian J. 2014, 9 (10), 2896–2907.
(4) Chakraborty, S.; Berke, H. Homogeneous Hydrogenation of Nitriles Catalyzed by Molybdenum and Tungsten Amides. ACS Catal. 2014, 4 (7), 2191–2194.
(3) Chakraborty, S.; Blacque, O.; Fox, T.; Berke, H. Highly Active, Low-Valence Molybdenum- and Tungsten-Amide Catalysts for Bifunctional Imine-Hydrogenation Reactions. Chem. - Asian J. 2014, 9 , 328–337.
(2) Chakraborty, S.; Blacque, O.; Fox, T.; Berke, H. Highly Efficient Large Bite Angle Diphosphine Substituted Molybdenum Catalyst for Hydrosilylation. ACS Catal. 2013, 3, 2208–2217.
(1) Jana, R.; Chakraborty, S.; Blacque, O.; Berke, H. Manganese and Rhenium Formyl Complexes of Diphosphanylborane Ligands: Stabilization of the Formyl Unit from Intramolecular B–O Bond Formation. Eur. J. Inorg. Chem. 2013 (26), 4574–4584.
Patent Application
“Manganese based complexes and uses thereof for homogeneous catalysis”, Milstein, David; Vogt, Matthias; Mukherjee, Arup; Espinosa-Jalapa, Noel Angel; Chakraborty, Subrata; Nerush, Alex, PCT Int. Appl. (2017), WO 2017137984 A1 20170817.
Book Chapter:
“Coexistence of Lewis Acid and Base Functions: A Generalized View of the Frustrated Lewis Pair Concept with Novel Implications for Reactivity”. Heinz Berke*, Yanfeng Jiang, Xianghua Yang, Chungfang Jiang, Subrata Chakraborty, Anne. Landwehr, Top Curr Chem. 2013, 334: 27–58.